Petrography and geochemistry of the Lower Cretaceous Deposits of the Vandam Zone (southern slope of the Greater Caucasus): insights into paleoweathering, provenance and tectonic setting
Guliyev E.Kh.
Ministry of Science and Education of the Republic of Azerbaijan, Institute of Geology and Geophysics, Azerbaijan H.Javid Ave., 119, Baku, AZ1143: guliyevemin@outlook.com
DOI: 10.33677/ggianas20240200136
Summary
This study examines the paleoweathering conditions, provenance, and tectonic setting of Neocomian deposits, focusing on the Kepuch and Gyrkhbulag Formations within the Vandam tectonic zone on the northern flank of the South-Caucasian microplate, characterized by complex Cretaceous flysch and volcanogenic formations. By integrating petrographic and geochemical data, this research aims to identify distinctive geochemical features reflecting provenance, weathering processes, and depositional environments, deepening the understanding of the regional geodynamic evolution. Petrographic analysis of the sandstones reveals a composition primarily consisting of rock fragments, quartz, and feldspar, with a significant clay matrix exceeding 15%, classifying them as lithic wackes and highlighting the dominance of volcanic and metamorphic rock fragments along with authigenic calcite cement. All geochemical proxies for paleoweathering, such as the Chemical Index of Alteration (CIA), Chemical Index of Weathering (CIW), and Plagioclase Index of Alteration (PIA), suggest that the source regions underwent a low to moderate degree of weathering. Provenance analysis suggests that the sediments are derived from a mixed source, primarily consisting of felsic and intermediate igneous rocks, consistent with a continental island arc tectonic environment. Discrimination diagrams – including SiO2 versus K2O/Na2O, Al2O3/SiO2 versus Fe2O3+MgO, La–Th–Sc, Ti/Zr versus La/Sc, and Eu/Eu*–GdN/YbN – place the samples within active continental margin and continental island arc fields, supporting a subduction-related sediment source. This analysis highlights the significant role of tectonic processes in shaping the geochemical characteristics of these siliciclastic rocks.
Keywords: provenance, tectonic setting, paleoweathering, Vandam zone, Kepuch and Gyrkhbulag Formations
REFERENCES
Abdullaev R.N., Mustafaev M.A., Samedova R.A., Shafiev Kh.I., Mamedov M.N. Petrology of Magmatic Complexes of the Southern Slope of the Greater Caucasus (Vandamskaya Zone). Elm. Baku. 1990 (in Russian).
Alizadeh Ak.A. (ed.). Geology of Azerbaijan. Volume 4: Tectonics. Nafta Press. Baku, 2005a, 580 p. (in Russian).
Alizadeh Ak.A. (ed.). Geology of Azerbaijan. Volume 1: Stratigraphy. Nafta Press. Baku, 2005b, 580 p. (in Russian).
Bhatia M.R. Plate tectonics and geochemical composition of sandstone. The Journal of Geology, Vol. 91,1983, pp. 611-627, http://dx.doi.org/10.1086/628815
Bhatia M.R., Crook K.A.W. Trace element characteristics of graywackes and tectonic setting discrimination of sedimentary basins. Contributions to Mineralogy and Petrology, Vol. 92(2), 1986, pp. 181-193, https://doi.org/10.1007/ BF00375292.
Cox R., Lowe D.R., Cullers R.L. The influence of sediment recycling and basement composition on evolution of mudrock chemistry in the Southwestern United States. Geochimica et Cosmochimica Acta, Vol. 59, No. 14, 1995, pp. 2919-2940, https://doi.org/10.1016/0016-7037(95)00185-9.
Fedo C.M., Nesbitt H.W., Young G.M. Unravelling the effects of potassium metasomatism in sedimentary rocks and paleosols, with implications for palaeo-weathering conditions and provenance. Geology, Vol. 23, No. 10, 1995, pp. 921-924, https://doi.org/10.1130/0091-7613(1995)023<0921: UTEOPM>2.3.CO;2.
Floyd P.A. and Leveridge B.E. Tectonic environment of the Devonian Gramscatho Basin South Cornwall: Framework mode and geochemical evidence from turbiditic sandstones. Journal of the Geological Society (London), Vol. 144, 1987, pp. 531-542, http://dx.doi.org/10.1144/gsjgs.144.4.0531.
Floyd P.A. and Leveridge B.E. Tectonic environment of the Devonian Gramscatho Basin South Cornwall: Framework Mode and Geochemical Evidence from Turbiditic Sandstones. Journal of the Geological Society (London), Vol. 144, 1987, pp. 531-542, http://dx.doi.org/10.1144/gsjgs.144. 4.0531.
Floyd P.A., Shail R., Leveridge B.E., Franke W. Geochemistry and provenance of Rhenoher-cynian synorogenic sandstone: Implications fortectonic environment discrimination. In: Developments in Sedimentary Provenance (Morton A., Todd S.P., Haughton P.D.W. eds), Geological Society Special Publication 57, 1990, pp. 173-88, Geological Society of London, London.
Floyd P.A., Winchester J.A. and Park R.G. Geochemistry and tectonic setting of Lewisian clastic metasediments from the Early Proterozoic Loch Maree Group of Gairloch, N.W. Scotland. Precambrian Research, Vol.45, 1989, pp. 203-214, http://dx.doi.org/10.1016/0301-9268(89)90040-5.
Harnois L. The CIW index: A new chemical index of weathering. Sedimentary Geology, Vol. 55, No. 3-4, 1988, pp. 319-322, https://doi.org/10.1016/0037-0738(88)90137-6.
Hauhnar M., Lalnunmawia J., Dawngliana O.M.S. Geochemistry of Barail sandstone in Champhai, Mizoram: Implications on provenance and weathering history. J. Earth Syst. Sci., Vol. 130, No. 27, 2021, pp. 2-19, https://doi.org/10.1007/s12040-020-01515-9.
Herron M.M. Geochemical classification of terrigenous sands and shales from core or log data. Journal of Sedimentary Petrology, Vol. 58, No. 5, 1988, pp. 820-829.
Kangarli T.N. Mass overthrust within the structure of Greater Caucasus (Azerbaijan). In: The modern problems of geology and geophysics of Eastern Caucasus and the South Caspian Depression. 34th International Geological Congress. Special Issue Papers. Nafta-Press. Baku, 2012, pp. 163-201.
Kroonenberg S.B. Effects of provenance, sorting and weathering on the geochemistry of fluvial sands from different tectonic and climatic environments. In: Proc. 29th Int. Geol. Congr. Part A. (Kumon F., Yu K.M. eds.), Kyoto, Japan 1992, VSP Publ., Utrecht, 1994, pp. 69-81.
McLennan S.M. Rare earth elements in sedimentary rocks: influence of provenance and sedimentary processes. In: Geochemistry and Mineralogy of Rare Earth Elements (Lipin B.R. and McKay G.A., eds.), De Gruyter. Berlin, Vol. 21, No. 1, 1989, pp. 169-200, https://doi.org/10.1515/97815015 09032-010.
McLennan S.M. Weathering and global denudation. The Journal of Geology, Vol. 101(2), 1993, pp. 295-303. https://doi.org/ 10.1086/648222.
Md. Masidul Haque, Mrinal Kanti Roy. Sandstone-Shale Geochemistry of Miocene Surma Group in Bandarban Anticline, SE Bangladesh: Implications for Provenance, Weathering, and Tectonic Setting. Earth Sciences, Vol. 9(1), 2020, 38-51, https://doi.org/10.11648/j.earth.20200901.15.
Murali A.V., Parthasarathy R., Mahadevan T.M., Das M.S. Trace element characteristics, REE patterns and partition coefficients of zircons from different geological environments – A case study on Indian zircons. Geochimica et Cosmochimica Acta, Vol. 47, 1983, pp. 2047-2052.
Nesbitt H.W. and Young G.M. Early Proterozoic climates and plate motions inferred from major element chemistry of lutites. Nature, Vol. 299, 1982, pp. 715-717, https://doi.org/10.1038/299715a0.
Nesbitt H.W. and Young G.M. Prediction of some weathering trends of plutonic and volcanic rocks based on thermodynamic and kinetic considerations. Geochimica et Cosmochimica Acta, Vol. 48, No. 7, 1984, pp. 1523-1534, DOI:10.1016/0016-7037(84)90408-3.
Pettijohn F.J., Potter P.E., Siever R. Sand and sandstone. Springer-Verlag. New York, 1973, 618 p.
Rodrigo J.D., Gabo-Ratio J.A.S., Queaño K.L., Fernando A.G.S., Silva L.P., Yonezu K., Zhang Y. Geochemistry of the Late Cretaceous Pandan Formation in Cebu Island, Central Philippines: Sediment contributions from the Australian plate margin during the Mesozoic. The Depositional Record, Vol. 6(2), 2020, pp. 309-330, DOI:10.1002/dep2.103.
Roser B.P. and Korsch R.J. Determination of Tectonic Setting of Sandstone-Mudstone Suites Using SiO2 Content and K2O/Na2O Ratio. Journal of Geology, Vol. 94, 1986, pp. 635-650, https://doi.org/10.1086/629071.
Rustamov M.I. Geodynamics and magmatism of the Zagros-Caucasus Segment in the Phanerozoic. Palmarium Academic Publishing. 2016, 543 p. (in Russian).
Schieber J. A combined petrographical-geochemical provenance study of the Newland formation, Mid-Proterozoic of Montana. Geological Magazine, Vol. 129, 1992, pp. 223-237.
Taylor S.R. and McLennan S.M. The continental crust: Its composition and evolution. Blackwell Scientific Publications. Oxford, 1985, pp. 1-312.
Taylor S.R., McLennan S.M. The continental crust: Its composition and evolution. Oxford, London, Edinburgh, Boston, Palo Alto, Melbourne: Blackwell Scientific. Geological Magazine, Vol. 122(6), 1985, pp. 673-674, DOI:10.1017/S0016756800032167.
DOI: 10.33677/ggianas20240200136