International scientific journal

ISSN: 2663-0419 (electronic version)

ISSN: 2218-8754 (print version)

International scientific journal

ISSN: 2663-0419 (electronic version)

ISSN: 2218-8754 (print version)

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Gold mineralization in oil fields of the South Caspian Basin. Discussion paper

Huseynov D.A.


Ministry of Science and Education of the Republic of Azerbaijan,
Institute of Geology and Geophysics, Azerbaijan 119, H.Javid ave., Baku, AZ1143: d_huseynov@yahoo.com

 

DOI: 10.33677/ggianas20240100121

Summary

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The basis of idea of the gold content of the South Caspian oil-and-gas bearing basin is the notion regarding the forming of gold-bearing catagenic solutions by the oil-gas generating Paleogene – Lower Miocene sediments which within the zone Volga-Don-Pre-Caucasus–Trans Caspian enclose the complex sulphide-phosphatic-rare metal-uranium deposits. In iron sulphides there are constant gold, cobalt, nickel, molybdenum, rhenium, rare copper, zinc, plumbum and arsenic, but in pyritiferous horizons of some regions there are often inclusions of native minerals – gold, bismuth, tin and copper.


The detail geologic-geophysical and isotopic-geohemical studies have showed that in the South-Caspian sedimentary basin in “oil-gas window” the catagenic aqueous solutions enriched with ore components were intensively generated along with formation of liquid and gaseous hydrocarbons. It is proved by high content and constant presence of gold, silver, copper, molybdenum, zinc, arsenic and other metals in oils, bitumens and formation waters. This stimulated the study of possibility of ore accumulations forming in the paleo-sources of the fluids’ catagenic discharge and confirmed our predictions regarding the noble metal and oil paragenesis in the South Caspian sedimentary basin.


The top-cut concentrations of gold and palladium as well as the indicators of the epithermal mineralization of gold of the Carlin-type – arsenic and barium – were revealed within the zone.


Such study for gold exploration within the South Caspian basin was performed for the first time. The obtained results open the basin’s prospects as the gold-oil-bearing one. The revealed gold-ore mineralization represents a discovery of a new genetic type of gold-ore mineralization in Azerbaijan also known worldwide as stratiform Carlin-type with microdissiminated, low content and significant reserves of gold.


Keywords:
gold, oil field, mineralization, noble-metal and oil paragenesis, centers of fluid discharge, geochemical anomaly, stratiform deposits

 

REFERENCES


Abercrombie H.J.  and Feng R. Geological setting and origin of microdisseminated Au-Ag-Cu minerals, Fort Mackay region, northeastern Alberta.  Geological Survey of Canada Bulletin, 500, 1997, pp. 247-277.


Agalarov M.S., Israelyan A.D., Sappo P.V., Akhmedova R.A. Content and type of distribution of some chemical elements in the system oil-rock-water within Muradkhanli field. Azerbaijan Oil Economy, 1980, No. 7, pp. 15-18 (in Russian).


Akhundov A.R., Sappo P.V. 1960. On issue of some microelements distribution in the formation waters of Productive Series of Balakhani-Sabunchi-Ramana field. Azerbaijan Oil Economy, No. 8, 1960, pp. 9-11 (in Russian).


Aliyev A.A., Huseynov D.A, Abbasov O., Rashidov T., Kangarli I. Mud volcanoes of Azerbaijan: The unique natural objects of the geoheritage. Geoheritage, Vol. 16(1), article id. 20, 2024, https://doi.org/10.1007/s12371-024-00931-3.


Alizade А.А., Guliyev I.S., Mamedov P.Z., Aliyeva E.G., Feyzullayev А.А., Huseynov D.A. Productive Series of Azerbaijan. In 2 volumes. Publishing House «Nedra», 2018, Vol. 1, 305 p. (in Russian). 


Babayev F.R. On geochemistry of oils in Azerbaijan marine deposits. Reports of Academy of Sciences of AzSSR, Vol. XL, No. 8, 1984, pp. 55-57 (in Russian).


Bagir-zade F.M., Narimanov A.A., Babayev F.R. Geologic-geochemical peculiarities of the fields of the Caspian Sea. Nedra. Moscow, 1988 (in Russian).


Bogashova L.G. Role of the halogen waters in forming of the mineral deposits. GEOS. Moscow, 2007, 168 p. (in Russian).


Burton J.C., Lawler J.P., Ayres D.E. Genesis of Carlin-type gold deposits. Geol. Soc. Am., Abstr. Programs; Vol/Issue: 17;/98. Annual meeting of the Geological Society of America; 28 Oct 1985; Orlando, FL, USA.


Cabri L.J., Chryssoulis S.L., DE Villiers J. P.R., Laflamme J.H.G., Buseck R. The nature of “invisible” gold in arsenopyrite. Can. Mineral., Vol. 27, 1989, pp. 353-362.


Cameron E.M. and Hattori K.H. Mobility of palladium in the surface environment: data from a regional lake sediment survey in northwestern Ontario. Geochemistry: Exploration, Environment, Analysis, Vol. 3, 2003, pp. 299-311.


Cline J. Timing of gold and arsenic sulfide mineral deposition at the Getchell Carlin-type gold deposit, North-Central Nevada. Economic Geology, Vol. 96, 2001, pp. 75-89.


Emeri K., Hunt D., Heys E. General review of problem of the thermal solutions and ore sediments of the Red Sea. The modern hydrothermal ore-forming. Mir. Moscow, pp. 7-25 (in Russian).


Faber E.Z. Isotope geochemistry of gaseous hydrocarbons: petroleum, natural gas and coal. Vol. 103, 1987, pp. 210-218 (in German).


Fedikow M.A.F., Bezys R.K., Bamburak J.D., Abercrombie H.J. The geological setting of prairie-type micro-disseminated gold mineralization in Manitoba. Abstracts book of Conference CIM, Vancouver 97, April 27-30, 1997, Vancouver, BC.


Fedikow M.A.F., Bezys R.K., Bamburak J.D., Abercrombie H.J. Prairie-type microdisseminated Au mineralization – a new deposit type in Manitoba's Phanerozoic rocks (NTS 63C/14). In: Manitoba Energy and Mines, Minerals Division, Report of Activities 1996, pp.108-121.


Feyzullayev A.A., Guliyev I.S., Tagiyev M.F. Source potential of the Mesozoic-Cenozoic rocks in the South Caspian Basin and their role in forming the oil accumulations in the Lower Pliocene reservoirs. Petroleum Geoscience, Vol. 7, No. 4, 2001, pp. 409-417.


Feyzullayev A.A., Huseynov D.A., Tagiyev M. Oil source rocks and geochemistry of hydrocarbons in South Caspian basin. In: South Caspian basin: geology, geophysics and gas content. Nafta-Press. Baku, 2004, pp. 286-321.


Feyzullayev А.А. Huseynov D.A., Rashidov T.M. Isotopic composition of the products of the mud volcanoes activity in the south-caspian basin in connection with petroleum potential of the deeply burried sediments. ANAS Transactions, Earth Sciences No. 1, 2022, pp. 68-80, DOI: https://doi.org/10.33677/ggianas20220100073 (in Russian).


Ge X., Shen Ch., He P., Jin Y., Li S., Chen Y. The roles of hydrocarbons on the mineralization of Carlin-type gold deposits, Nanpanjiang Basin, South China. Ore Geology Reviews, Vol. 149, 105107, 2022, pp. 1-15.


Guliyev I.S., Feyzullayev A.A., Huseynov D.A. Maturity level of oils contained in different age reservoirs in the South Caspian mega-Basin. Oil and gas geology, Moscow, No. 3, 2000, pp. 41-50.


Guliyev I.S., Feyzullayev A.A., Huseynov D.A. Isotope geochemistry of oils from fields and mud volcanoes in the South Caspian Basin, Azerbaijan. Petroleum Geoscience, Vol. 7, No. 4, 2001, pp. 409-417.


Guliyev I.S., Huseynov D.A., Feyzullayev A.A. Fluids of mud volcanoes in the Southern Caspian sedimentary basin: geochemistry and sources in light of new data on the carbon, hydrogen, and oxygen isotopic compositions. J. Geochemistry International, Moscow, Vol. 42, No. 7, 2004, pp. 688-695.


Guliyev I.S, Feyzullayev A.A., Huseynov D.A. Isotopic composition of carbon of oils of the South-Caspian megadepression. Azerb.Neft.Khozyavstvo, No. 6, 1999, p. 3-13 (in Russian).


Guliyev I.S.and Huseynov D.A. Relics of mud volcanoes in the sedimentary cover of the South Caspian Basin. Lithology and Mineral Resources, Vol. 50, No. 4, 2015, pp. 311-321.


Hausen D.M. Process mineralogy of auriferous pyritic ores at Carlin, Nevada. In: Process Mineralogy (Hausen D.M. and Park W.C., eds.), TMS, Warrendale, PA, 1981, pp. 271-289.


Hausen D.M., Ahlrichs J.W., Mueller W., Park W.C. Particulate gold occurrences in three Carlin carbonaceous ores. In: Process Mineralogy VI, (Hagni D., ed.), TMS, Warrendale, PA, 1986, pp. 193-214.


Hofstra A.H. and Cline J.S. Characteristics and models for Carlin-type gold deposits. Reviews in Economic Geology, Vol. 13, 2000, pp. 163-220.


Hulen J.B. and Collister J.W. The oil-bearing, Carlin-type gold deposits of Yankee Basin, Alligator Ridge District, Nevada. Economic Geology, Vol. 94, 1999, pp. 1029-1050.


Hulen J.B., Collister J.W., Curtiss D.K. The role of active and ancient geothermal processes in the generation, migration, and entrapment of oil in the Basin and Range Province, Western USA. Grant project DE-FG02-90ER14133 of University Utah. Salt Lake City, Utah, US, 1998.


Huseynov D.A. Origin of oils in the western part of the Kura South Caspian oil-gas bearing basins. Proceedings of 62d EAGE Conference, UK, Glasgow, 2000, P-20, http://dx.doi.org/ 10.3997/2214-4609-pdb.28.A55.


Huseynov D.A. Paragenesis of metals and oil-generating series in the South Caspian sedimentary basin. Proceedings of 16th Sedimentological Congress, South Africa, 8-12 July 2002, pp. 23-27.


Ilchik R.P. and Barton M.D. An amagmatic origin of Carlin-type gold deposits. Economic Geology and the Bulletin of the Society of Economic Geolocists, Vol. 92, No. 3, 1997, pp. 269-288.


Israelyan A.D. Microelements in ash of oils of the Maykopian formation of Azerbaijan. Proceedings of AzNII (AzNIPINeft), 1959, pp. 274-281 (in Russian).


Israelyan A.D. Trace elements in the Tertiary sediments of oil-bearing provinces of Azerbaijan (by spectral analysis data). Abstract of thesis, Baku, 1964 (in Russian).


Israelyan A.D., Akhmedova R.A., Aliyev G.-M.A. Microelements in ashes of oils of the Productive Series of Azerbaijan. Azerb.Neft.Khozyavstvo, No. 10, 1975, pp. 6-10 (in Russian).


Kuehn C.A. and Rose A.W. Carlin gold deposits, Nevada: Origin in deep zone of mixing between normally pressured and overpressured fluids. Economic Geology, Vol. 90, 1995, pp. 12-36.


Lebedev L.M., Nikitina I.B. Cheleken ore-forming system. Nauka. Moscow, 1983, 240 p. (in Russian).


Mekhtiyev Sh.F., Rakovski E.E., Mirzoyev R.Kh., Kharitonov V.M., Sadigov A.M. Metal content of the bituminous rocks of Azerbaijan. Proceedings of Academy of Sciences of the USSR. Geological series, No. 4, 1986, pp. 117-123 (in Russian).


Mirzoyev R.Kh. and Kharitonov V.M. On issue of study of the gold trace content in Azerbaijan oils. Azerbaijan Oil Economy, No. 11, 1982, pp. 15-18 (in Russian).


Olivo G.R., Gauthier M., Williams-Jones A.E., Levesque M. The Au-Pd mineralization at the Conceição Iron Mine, Itabira District, Southern Sгo Francisco Craton, Brazil: an example of a Jacutinga-type deposit. Economic Geology, Vol. 96, 2001, pp. 61-74.


Pushkina Z.V. Porous waters of the clayey rocks and their alterations along the section. Post-sedimentation alterations of quaternary and Pliocene clay deposits of Baku archipelago. Academy of Sciences of the USSR, Transactions, Vol. 115, Nauka. Moscow, 1965, pp. 160-203 (in Russian).


Radtke A.S. Geology of the Carlin gold deposit, Nevada. U.S. Geological Survey Professional Paper 1267, 1985, 124 p.


Rakovski E.E., Mirzoyev R.Kh., Kharitonov V.M. On study of gold distribution in oils of Lokbatan field. Azerb. Neft. Khozyavstvo, No. 8, 1985, pp. 8-13 (in Russian).


Seedorff E. and Barton M.D. Enigmatic origin of Carlin-type deposits: An amagmatic solution? SEG Newsletter, No. 59, 2004, pp. 14-18.


Togashi Y. Geological characteristics of the sediment hosted, disseminated gold deposits in the Western United States of America. In: The series of mineral concentrations and hydrocarbon accumulations in the ESCAP region. Volume 6 – Epithermal gold in Asia and the Pacific (ST/ESCAP/1023). United Nations publication. 1992, 224 p.


Turekian K.K. and Wedepohl K.H. Distribution of the elements in some major units of the Earth’s crust. Geological Society of America Bulletin, Vol. 72, 1961, pp. 175-192.


Yushko-Zakharova O.E., Ivanov V.V., Soboleva L.N. et al. Minerals of the noble metals. Nedra. Moscow, 1986, 272 p. (in Russian).

 

DOI: 10.33677/ggianas20240100121